George Clooney, 2006

George nabbed his second win in 2006 while he was in between Ocean's Eleven movies — the franchise that feeds the Sexiest Men Alive pool. That year he starred in The Good German and won an Oscar for his role in Syriana. As one of the hottest philanthropists in Hollywood, George was heavily involved in advocating a resolution of the Darfur conflict that year. He even spoke at a 2006 Save Darfur rally in Washington DC and spent time in Chad and Sudan with his father to make a TV documentary about Darfur's refugees.

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